Boosting NiO Catalytic Activity by x wt % F?ions and K <sub>2</sub> O for the Production of Methyl Ethyl Ketone (MEK) via Catalytic Dehydrogenation of 2?Butanol

نویسندگان

چکیده

Herein, the synthesis of pure and modified mesoporous nanocrystalline NiO is reported. The catalyst was with different wt % F-ions or K2O used to produce Methyl ethyl ketone (MEK) as a potential fuel/solvent. XRD analysis promoted catalysts confirmed formation Ni-metal covered by host oxide, compared NiO, especially for x F-ions. CO2-TPD results demonstrated existence basic sites over these varying strength. catalytic conversion sec-butanol (SB) into MEK parent showed 52 76.8 SB at 250 275 °C, respectively, higher selectivity >96 %. Among catalysts, NiO-10 F? NiO-1 99 95 conversion, retaining ?96 activity, most active correlated presence Ni/NiO interfaces, types sites, strong surface area porosity measurements.

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ژورنال

عنوان ژورنال: Chemcatchem

سال: 2021

ISSN: ['1867-3899', '1867-3880']

DOI: https://doi.org/10.1002/cctc.202001954